Syntheses and properties of B-C-N and BN nanostructures

The current status of research on boron-carbon-nitrogen (B-C-N) and boron nitride (BN) nanotubes is presented. The latest achievements in syntheses, analyses and property measurements of these nanoscale tubular architectures are reviewed. The characteristic features of B-C-N and BN nanotubes, compared with conventional C nanotubes, are paid special attention. In particular, the latest breakthroughs in the chemical vapour deposition synthesis of BN nanotubes and an insight into their unique structures are highlighted. A wide range of potential applications is also envisaged, based on the recent progress, which includes pioneering results in BN nanocable fabrication, gas adsorption, electron transport and field emission measurements.     

Hiding an image with a light-scattering medium and use of a contrast-discrimination method for readout

Hiding image data with a material such as a light-scattering medium is useful as an initial stage of data protection, because the hidden image can be detected only by observation with a specific technique. A light-scattering medium is used to hide the image data, and a low-temporal-coherence interferometer performs the readout processing. A new readout method for detecting pixel values of the image is proposed to overcome spatial variation of the light intensity and distortion of the interference fringes. The introduction of spatial coding further improves the performance by overcoming spatial variations of the light-scattering medium and variations in the reflectance of given pixels.     

Polymer film-type channel electron multipliers: Their characteristics and comparison with bulk-type flexible multipliers

Polymer film-type channel electron multipliers (CEMs) were developed and their characteristics investigated in comparison with bulk-type flexible CEM. As film-type CEMs, a paint-coating-type CEM and a solvent-etching-type CEM were fabricated. The paint-coating-type CEM is made by coating a “paint” which is prepared by dissolving in a solvent an electronically conductive polymeric composition having a high secondary electron emission yield. Up to the present study the mean gain of the film-type CEM, in spite of the lower resistivity of the dynode, seems to be slightly more dependent on the count rate than that of the bulk-type CEM made of the same material. However, the convenience of fabricating the dynode film by coating the dynode-forming paint on the internal surface of any shaped tube or a flexible polymer tube would overcome the slight disadvantage mentioned above.     

Portable sick house syndrome gas monitoring system based on novel colorimetric reagents for the highly selective and sensitive detection of formaldehyde

Formaldehyde (HCHO) emitted from the furniture and the walls in the rooms injures the eyes, nose, and respiratory organs and causes allergies, which is called sick house syndrome. We designed and synthesized novel colorimetric HCHO-sensing molecules (KD-XA01 and KD-XA02) which possess an enaminone structure and developed a hand-held instrument to monitor indoor HCHO gas with the use of KD-XA01. These sensing molecules produced speedy color changes from colorless to yellow under mild conditions, which was caused by the fact that the enaminone structure in the reagent reacts with HCHO to give a lutidine derivative. This reaction took place not only in the solution phase but also in the solid phase (surface of the cellulose paper). To take advantage of this phenomena, a handy and rapid monitoring system has been developed for detecting indoor HCHO gas using a highly sensitive and selective detection tablet constructed from the porous cellulose paper that contains silica gel as an adsorbent, KD-XA01, and phosphoric acid under optimum conditions. This instrument detected the surface color change of the tablet from white to yellow, which was monitored as a function of the intensity of the reflected light illuminated by an LED (475 nm). The response was proportional to the HCHO concentration at a constant sampling time and flow rate; 0.05 ppm HCHO, which is under the standard value set by the World Health Organization, was able to be detected in 5 min. The detection limit was 0.005 ppm. This monitoring system was not interfered by carbonyl compounds such as acetaldehyde and acetone, alcohols, hydrocarbons, and typical gases such as carbon monoxide, carbon dioxide, nitrogen dioxide, etc., which contributes to the measurement of correct HCHO concentrations. It was possible to monitor the HCHO gas in the room of a new apartment and school using this instrument; the response values were in good agreement with those obtained by the standard DNPH method. This highly sensitive, selective, and handy HCHO gas monitor is widely applicable and convenient for users who are not specialists in this field.     

Superior electrocatalytic activity of mesoporous Au film templated from diblock copolymer micelles

Mesoporous Au films consisting of a network of interconnected Au ligaments around ultra-large pores were found to exhibit a promising electrocatalytic activity towards sluggish reactions. Mesoporous Au films with pore sizes up to 25 nm were successfully fabricated using a polymeric micelle approach. A superior catalytic activity of the mesoporous Au films towards methanol oxidation was confirmed, which was thoroughly analyzed and compared with that of other Au materials. An intrinsic investigation on the high catalytic activity revealed that the superior performance of the as-prepared mesoporous Au film was related to its unique atomic structures around the mesopores with well-crystallized facets and several step/kink sites on the Au surfaces. These findings showcase a strategic and feasible design for preparing highly active Au-based catalysts that could be used as promising candidates in electrocatalytic applications.

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Transformation of Lower Alkanes into Aromatic Hydrocarbons over ZSM-5 Zeolites

Much attention has been paid to the transformation of lower alkanes such as propane and butanes into aromatic hydrocarbons from both industrial and academic points of view. The aromatic hydrocarbons can be utilized as a booster for high octane number gasoline and are fundamental raw chemicals in petroleum chemistry. The activation of lower alkanes is an intriguing subject. In early work, Csicsery [1–5] described dehydrocyclodimerization of lower alkanes over bifunctional catalysts such as platinum on alumina and Cr₂O₃ on alumina.     

A Numerical Method of Macrosegregation Using a Dendritic Solidification Model,and Its Applications to Directional Solidification <Emphasis Type="Italic">via</Emphasis> the Use of Magnetic Fields

A numerical method for analyzing solidification phenomena of multicomponent alloys is presented. This method consists of macroscopic transport governing equations expressed in terms of a nonlinear multicomponent alloy model, which is coupled with the microscopic dendritic solidification model to estimate permeability. Numerical simulations were performed for channel segregation in a steel ingot and for freckles in a Ni-base IN718 remelted ingot and in Ni-10 wt pct Al directionally solidified (DS) ingots. The results show good agreement with experimental observations. The electromagnetic (EM) braking effect by static magnetic field was incorporated into the numerical method, and the anisotropic behavior of magnetic field was investigated on the DS Ni-10 wt pct Al ingots. Application of relatively low magnetic fields in the transverse to the growth direction (B _x or B _y ) resulted in formation of distorted freckles as a result of the nonuniform liquid flow induced in the transverse direction. It is shown that a considerably high magnetic field is required to suppress the distorted freckles and other freckles developed in longitudinal direction. However, there is a risk of the breakdown of DS. On the other hand, when applying the magnetic fields parallel to the growth direction (B _z ), the number of freckles inversely increased at low magnetic fields, but the freckles were eliminated by about the same level of high magnetic field as that of B _x or B _y . Because the parallel magnetic field suppresses the liquid flow vector components uniformly within the transverse plane, the nonuniform flow does not occur in the transverse directions. As a result, it suppresses the flow in the growth direction. It is envisioned that the application of the parallel magnetic field is beneficial in the commercial production of DS castings.     

Application of a chemical heat pump to a cogeneration system

The feasibility of a proposed system that combines a magnesium oxide/water chemical heat pump and a diesel engine as a cogeneration system is discussed based on experimental results. The combined system is intended to utilize the waste heat discharge from the engine by means of the chemical heat pump and to level the heat supply load of the engine, allowing enhanced energy utilization. The thermal performance of the chemical heat pump in the cogeneration system is estimated based on the results of a packed‐bed experiment. The estimation indicates that by storing the waste heat from the engine during low demand periods, the cogeneration system can produce more than several times the standard thermal output of the diesel engine during peak demand periods. Copyright © 2001 John Wiley & Sons, Ltd.